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Character Unlock Requirements

Name How to Unlock?
Seto Kaiba Pick as a starter character (or reach Stage 15 if you choose Yami Yugi as a starter).
Mai Valentine Reach Stage 10.
Yami Yugi Pick as a starter character (or reach Stage 15 if you choose Seto as a starter).
Joey Wheeler Reach Stage 3.
Tea Gardner Reach Stage 5.
Weevil Underwood Beat Standard Duelists 100 times.
Rex Raptor Reach Stage 21.
Mako Tsunami Conduct Tribute Summons 150 times.
Bandit Keith Beat Legendary Duelists 50 times.
Odion Activate Trap cards 300 times.
Ishizu Ishtar Summon LIGHT-attribute monster 200 times.
Maximillion Pegasus Earn 250,000 points at Pegasus unlock event.
Yami Bakura Obtainable by unlocking him during the "Fear the Deck of Terror: The Destiny Board of Doom" event.
Yami Marik Score 150,000 total points during the Attack of the Rare Hunters! Event.
Standard Duelist Standard Duelists and the Vagabond randomly appear across Duel World.
Yugi Muto Reach Stage 13 Unlock Missions Achieve 1 No Damage win(s) in Duels against Seto Kaiba at Level 30 using Yami Yugi Achieve 1 win(s) with 1000 or less LP left in Duels against Joey Wheeler at Level 30 using Yami Yugi. Use Level 7 or higher Monster cards 2 time(s) in one Duel using Yami Yugi. Play as Joey Wheeler and win 1 Duel(s) against Yami Yugi at Level 40 in Duel World. Achieve 1 win(s) with 1000 or less LP left in Duels against Yami Yugi at Level 40 using Seto Kaiba.
Super Joey Currently not available.
Paradox Brothers Earn 180,000 points during the Paradox Brothers Event.
Mokuba Kaiba Reach Stage 13 (DM).
Yami Bakura - Destiny Board of Doom Obtainable by unlocking him during the "Fear the Deck of Terror: The Destiny Board of Doom" event.
Arkana Unlock Missions Summon "Dark Magician" 2 time(S) in 1 Duel against Arkana at level 30 using Yami Yugi. Reduce your opponent's LP to 0 by inflicting battle damage with Dark Magician Girl in a Duel against Arkana at level 30 using Yami Yugi. Achieve 1 win(s) with 1000 of less LP left in Duels against Arkana at level 30 using Yami Yugi. Use a Spell Card 4 time(s) in one Duel World (DM) Duel. Achieve 3 win(s) using only Spellcaster-Type Monster Cards in Duel World (DM) Duels.
Elegant Mai Currently not available.
Jaden Yuki Summon 10 Warrior-type Monsters in Duels.
Aster Phoenix Summon 200 Dark-attribute Monsters. Unlock Missions Successfully perform 2 Fusion Summon(s) in one Duel. Achieve 3 win(s) without using any level 5 or higher Monster Cards Win 1 Duel(s) against Aster Phoenix at Level 30 in Duel World
Jesse Anderson Accumulate 200,000 points during the event "Awaken! Rainbow Dragon!"
Chazz Princeton Reach Stage 6 in GX world. Unlock Missions Achieve 1 Comeback Victory(ies) in Duels against Chazz Princeton using Jaden Yuki. Summon Thunder-Type Monster(s) 3 time(s) in total. Use Trap Cards 5 times.
Syrus Truesdale Earn 4400 points during the Syrus Truesdale's Road to Duel Links event.
Alexis Rhodes Reach Stage 10 in GX world. Unlock Missions: Successfully perform 3 Ritual Summons. Win 1 Duel(s) against Alexis Rhodes at level 20 in Duel World Collect 5 WATER Attribute Cards.
Dr. Vellian Crowler Unlock Missions Summon "Elemental HERO Flame Wingman" 1 time(s) while playing as Jaden Yuki, in a Duel against Dr. Vellian Crowler at level 30. Inflict 2000 or more points of effect damage with a single effect activation in a Duel against Dr. Vellian Crowler at level 30 using Jaden Yuki Achieve 1 Comeback Victory(ies) in Duels against Dr. Vellian Crowler at level 30 using Jaden Yuki Use level 7 of higher Monster Cards 3 time(s) in one Duel World (GX) Duel. Achieve 3 win(s) using only Machine-Type Monster Cards in Duel World (GX) Duels.
Bastion Misawa Achieve 50 win(s) with 3 or less Cards left in your Deck. Unlock Missions: Achieve 1 win(s) using only WATER Monster Cards. Achieve 1 win(s) using only FIRE Monster Cards. Achieve 1 win(s) using only EARTH Monster Cards. Achieve 1 win(s) using only WIND Monster Cards.
Bonz Reach Stage 13 (DM).